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Main‐Group‐Metal and Transition‐Metal Complexes Containing Fluorinated β‐Diketiminate Ligands
Author(s) -
Huse Kevin,
Wölper Christoph,
Schulz Stephan
Publication year - 2018
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201800414
Subject(s) - chemistry , transition metal , elemental analysis , infrared spectroscopy , metal , ligand (biochemistry) , crystallography , spectroscopy , nuclear magnetic resonance spectroscopy , group (periodic table) , single crystal , main group element , stereochemistry , inorganic chemistry , organic chemistry , catalysis , biochemistry , physics , receptor , quantum mechanics
The synthesis of fluorinated β‐diketimine LH 1 (L = HC[C(CF 3 )NC 6 F 5 ] 2 ) and its reactions with main‐group‐metal and transition‐metal complexes, yielding LAlMe 2 4 , LZnEt 5 , LCu(C 6 D 6 ) 6 and LCuCO 7 , is reported. 1 – 7 were characterized by IR and NMR spectroscopy ( 1 H, 13 C, 19 F), elemental analysis and single‐crystal X‐ray diffraction. The C 6 F 5 substituents strongly reduce the π‐back‐bonding capacity of the β‐diketiminate ligand as was shown for 7 by IR spectroscopy.
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