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Front Cover: Reactivity of a (Benzene)Ruthenium(II) Cation on a Di‐lacunary γ‐Keggin‐Type Silicotungstate and Synthesis of a Mono‐(Benzene)Ruthenium(II)‐Attached γ‐Keggin‐Type Silicotungstate (Eur. J. Inorg. Chem. 17/2018)
Author(s) -
Kikuchi Masaya,
Ota Hiromi,
López Xavier,
Nakaya Toshimi,
Tsunoji Nao,
Sano Tsuneji,
Sadakane Masahiro
Publication year - 2018
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201800314
Subject(s) - lacunary function , chemistry , ruthenium , front cover , benzene , crystallography , type (biology) , cover (algebra) , stereochemistry , inorganic chemistry , catalysis , organic chemistry , mechanical engineering , ecology , mathematics , pure mathematics , engineering , biology
The Front Cover shows the structure of a mono‐(benzene)Ru‐attached di‐lacunary (defect) γ‐Keggin‐type silicotungstate, [γ‐SiW 10 O 36 ] 8– . We found that the (C 6 H 6 )Ru 2+ first reacts with three bridging oxygen atoms of the non‐lacunary site of the di‐lacunary γ‐Keggin‐type silicotungstate to form [γ‐SiW 10 O 36 Ru(C 6 H 6 )] 6– ; it then reacts with the terminal oxygen atoms of the lacunary site to form a 2:1 [γ‐SiW 10 O 36 {Ru(C 6 H 6 )} 2 ] 4– complex. More information can be found in the Full Paper by M. Sadakane et al. For more on the story behind the cover research, see the Cover Profile .