Front Cover: Reactivity of a (Benzene)Ruthenium(II) Cation on a Di‐lacunary γ‐Keggin‐Type Silicotungstate and Synthesis of a Mono‐(Benzene)Ruthenium(II)‐Attached γ‐Keggin‐Type Silicotungstate (Eur. J. Inorg. Chem. 17/2018) | Zendy

Kikuchi Masaya | Zendy; Ota Hiromi | Zendy; López Xavier | Zendy; Nakaya Toshimi | Zendy; Tsunoji Nao | Zendy; Sano Tsuneji | Zendy; Sadakane Masahiro | Zendy

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Front Cover: Reactivity of a (Benzene)Ruthenium(II) Cation on a Di‐lacunary γ‐Keggin‐Type Silicotungstate and Synthesis of a Mono‐(Benzene)Ruthenium(II)‐Attached γ‐Keggin‐Type Silicotungstate (Eur. J. Inorg. Chem. 17/2018)

Author(s) -

Kikuchi Masaya,

Ota Hiromi,

López Xavier,

Nakaya Toshimi,

Tsunoji Nao,

Sano Tsuneji,

Sadakane Masahiro

Publication year - 2018

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201800314

Subject(s) - lacunary function , chemistry , ruthenium , front cover , benzene , crystallography , type (biology) , cover (algebra) , stereochemistry , inorganic chemistry , catalysis , organic chemistry , mechanical engineering , ecology , mathematics , pure mathematics , engineering , biology

The Front Cover shows the structure of a mono‐(benzene)Ru‐attached di‐lacunary (defect) γ‐Keggin‐type silicotungstate, [γ‐SiW 10 O 36 ] 8– . We found that the (C 6 H 6 )Ru 2+ first reacts with three bridging oxygen atoms of the non‐lacunary site of the di‐lacunary γ‐Keggin‐type silicotungstate to form [γ‐SiW 10 O 36 Ru(C 6 H 6 )] 6– ; it then reacts with the terminal oxygen atoms of the lacunary site to form a 2:1 [γ‐SiW 10 O 36 {Ru(C 6 H 6 )} 2 ] 4– complex. More information can be found in the Full Paper by M. Sadakane et al. For more on the story behind the cover research, see the Cover Profile .

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