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Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu I Ions
Author(s) -
Moussa Mehdi Elsayed,
Welsch Stefan,
Lochner Matthias,
Peresypkina Eugenia V.,
Virovets Alexander V.,
Scheer Manfred
Publication year - 2018
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201800112
Subject(s) - chemistry , cationic polymerization , group 2 organometallic chemistry , pyridine , ion , polymer , ligand (biochemistry) , crystallography , bipyridine , organometallic chemistry , medicinal chemistry , stereochemistry , inorganic chemistry , polymer chemistry , crystal structure , molecule , organic chemistry , biochemistry , receptor
A multicomponent approach of the P n ligand complex [Cp*Fe(η 5 ‐P 5 )] ( 1 : Cp* = η 5 ‐C 5 Me 5 ) with the ditopic organic linkers 4,4′‐bipyridine ( 2 ) or trans ‐1,2‐di(pyridine‐4‐yl)ethene ( 3 ) in the presence of Cu I salts of the anions [BF 4 ] – and [PF 6 ] – or the coordinating anion Br – , leads to the formation of four novel organometallic–organic hybrid polymers: the cationic 1D polymeric compounds [Cu 4 {Cp*Fe(µ 3 ,η 5:1:1 ‐P 5 )} 2 (µ,η 1:1 ‐C 10 H 8 N 2 ) 4 (CH 3 CN) 4 ] n [BF 4 ] 4n ( 4 ) and [Cu 4 {Cp*Fe(µ 3 ,η 5:1:1 ‐P 5 )} 2 (µ,η 1:1 ‐C 10 H 8 N 2 ) 4 (CH 3 CN) 4 ] n [PF 6 ] 4n ( 5 ) as well as the unique neutral threefold 2D → 2D interpenetrated networks [Cu 2 Cl 2 {Cp*Fe(µ 3 ,η 5:1:1 ‐P 5 )}(µ,η 1:1 ‐C 12 H 10 N 2 )] n ( 6 ) and [Cu 2 Br 2 {Cp*Fe(µ 3 ,η 5:1:1 ‐P 5 )}(µ,η 1:1 ‐C 10 H 8 N 2 )] n ( 7 ).