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Facile Silylation of Cyclitols Using Silyl Bis(triflates)
Author(s) -
Topp Anke,
Köckerling Martin,
Reinke Helmut,
Miethchen Ralf,
Mamat Constantin
Publication year - 2018
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201701327
Subject(s) - silylation , chemistry , trifluoromethanesulfonate , silane , organic chemistry , silanes , combinatorial chemistry , catalysis
Novel silylated diols and polyols were prepared using a recently developed synthesis route with bifunctionalized silyl triflates. These silyl derivatives include two triflate functions, which allow a selective protection of two hydroxy groups. Moreover, the conformation of the silyl chain in the silane backbone led to exceptional UV properties.