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Synthesis and Reactivity of Thiolate‐Bridged Ni II M I Heterodinuclear Complexes (M = Rh, Ir) with an S‐Bidentate NiP 2 S 2 Metalloligand
Author(s) -
Kure Bunsho,
Sano Mikie,
Watanabe Natsuki,
Nakajima Takayuki,
Tanase Tomoaki
Publication year - 2017
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201700937
Subject(s) - chemistry , hydride , denticity , reactivity (psychology) , crystallography , cover (algebra) , metal , tantalum , silylation , stereochemistry , crystal structure , catalysis , organic chemistry , medicine , alternative medicine , pathology , mechanical engineering , engineering
Invited for the cover of this issue is the group of Tomoaki Tanase at Nara Women's University, Japan. The cover image shows the transformation of a low‐valent dithiolate‐bridged heterodinuclear complex into two different types of hydride silyl complexes by treatment with hydrosilanes, where the hydride ligands are stabilized by semibridging between two metal centers of a “dimetal butterfly”.