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Front Cover: Synthesis and Reactivity of Thiolate‐Bridged Ni II M I Heterodinuclear Complexes (M = Rh, Ir) with an S‐Bidentate NiP 2 S 2 Metalloligand (Eur. J. Inorg. Chem. 35/2017)
Author(s) -
Kure Bunsho,
Sano Mikie,
Watanabe Natsuki,
Nakajima Takayuki,
Tanase Tomoaki
Publication year - 2017
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201700936
Subject(s) - chemistry , front cover , hydride , denticity , reactivity (psychology) , cover (algebra) , crystallography , metal , silylation , stereochemistry , medicinal chemistry , crystal structure , catalysis , organic chemistry , mechanical engineering , medicine , alternative medicine , pathology , engineering
The Front Cover shows the transformation of a low‐valent dithiolate‐bridged heterodinuclear complex into two different types of hydride silyl complexes by treatment with hydrosilanes, where the hydride ligands are stabilized by semibridging between two metal centers of a “dimetal butterfly”. These results demonstrate that flexible dithiolate‐bridged heterodinuclear complexes have the potential to stabilize small inorganic and organic ligands in their “butterfly cleft”. More information can be found in the Full Paper by B. Kure, T. Tanase et al. For more on the story behind the cover research, see the Cover Profile .