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Visible‐Light‐Driven Photocatalytic H 2 O 2 Production on g‐C 3 N 4 Loaded with CoP as a Noble Metal Free Cocatalyst
Author(s) -
Peng Yulan,
Wang Lingzhi,
Liu Yongdi,
Chen Haijun,
Lei Juying,
Zhang Jinlong
Publication year - 2017
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201700930
Subject(s) - photocatalysis , catalysis , chemistry , composite number , visible spectrum , noble metal , nanoparticle , irradiation , chemical engineering , nanotechnology , nuclear chemistry , materials science , composite material , organic chemistry , optoelectronics , physics , nuclear physics , engineering
A composite catalyst combining CoP with g‐C 3 N 4 was explored for the photocatalytic production of H 2 O 2 under visible‐light irradiation. The composite catalyst was fabricated by growth of CoP nanoparticles on the surface of g‐C 3 N 4 . The CoP nanoparticles were well dispersed on the surface of g‐C 3 N 4 and could interact with g‐C 3 N 4 to improve charge separation and electron transfer. The composite catalyst showed superior catalytic activity compared with pure CoP or g‐C 3 N 4 under visible‐light irradiation. The optimal catalyst with 1.76 wt.‐% CoP loading exhibited the best photocatalytic efficiency with an H 2 O 2 production of 140 µ m in 2 h, which is about 4.6 and 23.3 times those of pure g‐C 3 N 4 and pure CoP, respectively. A possible mechanism for the visible‐light‐driven photocatalytic production of H 2 O 2 is proposed. The composite catalyst exhibited stable performance without obvious loss of catalytic activity after seven successive runs, and thus has good application prospects in sustainable H 2 O 2 production.