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Structural Effect of the Pendant Unit in Thiocyanate‐Free Ru II Sensitizers on the Dye‐Sensitized Solar Cell Performance
Author(s) -
Tamura Rei,
Kono Takahiro,
Mori Shogo,
Kimura Mutsumi
Publication year - 2017
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201700899
Subject(s) - chemistry , ruthenium , dye sensitized solar cell , triphenylamine , photochemistry , thiocyanate , redox , terpyridine , energy conversion efficiency , alkoxy group , electron transfer , intermolecular force , solar cell , oxidizing agent , alkyl , inorganic chemistry , organic chemistry , molecule , catalysis , metal , physics , optoelectronics , electrode , electrolyte , thermodynamics
A combination of Ru complex sensitizers and Co complex redox couples for dye‐sensitized solar cells (DSSCs) generally results in low power conversion efficiency. This has been suggested to be from undesired electron transfer due to strong intermolecular interactions between the dye and the redox couple. To retard the interactions, two thiocyanate‐free ruthenium (Ru) sensitizers were synthesized with a terpyridine attached that has a triphenylamine (TPA) unit with branched alkoxy chains. The main difference between the two dyes is the angle of the three phenyl rings in the TPA unit. The DSSCs using both the new dyes show higher short‐circuit currents and open‐circuit voltages in comparison with those using a Ru complex dye with nonbranched alkyl chains. The Ru sensitizer with a more twisted TPA unit displays relatively high power conversion efficiency without coadsorption of chenodeoxycholic acid, suggesting less intermolecular interaction among dyes and thus also with Co complex redox couples.