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Synthesis, Characterisation and Hydrogen Bonding of Isostructural Group 10 Metal Halido Complexes Bearing a POCOP Ligand
Author(s) -
Joksch Markus,
Haak Julia,
Spannenberg Anke,
Beweries Torsten
Publication year - 2017
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201700680
Subject(s) - isostructural , chemistry , triclinic crystal system , ligand (biochemistry) , crystallography , hydrogen bond , palladium , nickel , stereochemistry , crystal structure , molecule , organic chemistry , biochemistry , receptor , catalysis
An isostructural series of nickel, palladium and platinum halido complexes of the type [(POCOP)MX] [POCOP = κ 3 ‐C 5 H 3 ‐2,6‐(OP t Bu 2 ) 2 ; X = F, Cl, I] was prepared and fully characterised. Molecular structures of complexes 1‐I , 2‐I , 3‐Cl and 3‐I are reported and show the typical distorted square‐planar coordination geometries. In the presence of HF, Ni and Pt fluorido complexes 1‐F and 3‐F show pronounced hydrogen bonding to HF to form bifluorido complexes 1‐FHF and 3‐FHF , respectively, which were characterised by X‐ray analysis. In the solid state, all complexes are isomorphous and crystallise in the triclinic space group P 1.