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Bis(4‐methylbenzoxazol‐2‐yl)methanide in s‐Block Metal Coordination
Author(s) -
Koehne Ingo,
HerbstIrmer Regine,
Stalke Dietmar
Publication year - 2017
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201700501
Subject(s) - chemistry , homoleptic , alkaline earth metal , magnesium , alkali metal , metal , ligand (biochemistry) , potassium , coordination complex , medicinal chemistry , solid state , stereochemistry , inorganic chemistry , crystallography , organic chemistry , biochemistry , receptor
On the basis of the bis(4‐methylbenzoxazol‐2‐yl)methanide ligand three new alkali or alkaline earth metal compounds were synthesized, and their solid‐state structures are discussed in detail. On the way to new alkaline earth metal species a promising potassium precursor complex [K{(4‐MeNCOC 6 H 3 ) 2 CH}{η 5 ‐K(4‐MeNCOC 6 H 3 ) 2 CH}(THF)] ∞ ( 2 ) and a homoleptic magnesium [Mg{(4‐MeNCOC 6 H 3 ) 2 CH} 2 ] ( 3 ) and calcium complex [Ca{(4‐MeNCOC 6 H 3 ) 2 CH} 2 (THF) 2 ] · THF ( 4 ) were obtained.