Premium
Highly Efficient Synthesis of Boron‐ and Germanium‐Substituted Unsymmetrical Disilazanes
Author(s) -
Kaźmierczak Joanna,
Kuciński Krzysztof,
SzudkowskaFrątczak Justyna,
Hreczycho Grzegorz
Publication year - 2017
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201700083
Subject(s) - chemistry , germanium , catalysis , boron , combinatorial chemistry , selectivity , nanotechnology , simplicity , organic chemistry , inorganic chemistry , silicon , philosophy , materials science , epistemology
We recently reported on the successful use of the Karstedt catalyst for the synthesis of organofunctionalized disilazanes, and the aim of this work was to check the activity of this catalyst in the preparation of novel unsymmetrical boron‐ and germanium‐functionalized disilazanes. High selectivity, relatively mild conditions, and the simplicity of the experimental techniques are favorable features of this catalytic system. These new multielement derivatives of disilazanes can be used as silylating agents to introduce functional groups on the surfaces of organic and inorganic materials.