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Oxidative Addition of Aryl Halides to Cationic Bis(phosphane)rhodium Complexes: Application in C–C Bond Formation
Author(s) -
König Anja,
Fischer Christian,
Alberico Elisabetta,
Selle Carmen,
Drexler HansJoachim,
Baumann Wolfgang,
Heller Detlef
Publication year - 2017
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201700051
Subject(s) - chemistry , rhodium , iodobenzene , cationic polymerization , oxidative addition , aryl , halide , catalysis , nuclear magnetic resonance spectroscopy , medicinal chemistry , spectroscopy , oxidative coupling of methane , photochemistry , polymer chemistry , organic chemistry , alkyl , physics , quantum mechanics
The oxidative addition of chloro‐, bromo‐ and iodobenzene to the cationic bis(phosphane)rhodium complex [Rh(DIPAMP)(MeOH) 2 ]BF 4 was investigated. The resulting complexes were characterized by X‐ray analysis and NMR spectroscopy and applied as catalysts in classical cross‐coupling reactions. Product inhibition was observed and quantified by UV/Vis and NMR spectroscopy.