Oxidative Addition of Aryl Halides to Cationic Bis(phosphane)rhodium Complexes: Application in C–C Bond Formation | Zendy

König Anja | Zendy; Fischer Christian | Zendy; Alberico Elisabetta | Zendy; Selle Carmen | Zendy; Drexler HansJoachim | Zendy; Baumann Wolfgang | Zendy; Heller Detlef | Zendy

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Oxidative Addition of Aryl Halides to Cationic Bis(phosphane)rhodium Complexes: Application in C–C Bond Formation

Author(s) -

König Anja,

Fischer Christian,

Alberico Elisabetta,

Selle Carmen,

Drexler HansJoachim,

Baumann Wolfgang,

Heller Detlef

Publication year - 2017

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201700051

Subject(s) - chemistry , rhodium , iodobenzene , cationic polymerization , oxidative addition , aryl , halide , catalysis , nuclear magnetic resonance spectroscopy , medicinal chemistry , spectroscopy , oxidative coupling of methane , photochemistry , polymer chemistry , organic chemistry , alkyl , physics , quantum mechanics

The oxidative addition of chloro‐, bromo‐ and iodobenzene to the cationic bis(phosphane)rhodium complex [Rh(DIPAMP)(MeOH) 2 ]BF 4 was investigated. The resulting complexes were characterized by X‐ray analysis and NMR spectroscopy and applied as catalysts in classical cross‐coupling reactions. Product inhibition was observed and quantified by UV/Vis and NMR spectroscopy.

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