Single‐Molecule‐Magnet Behavior in a Calix[8]arene‐Capped {Tb 6  III Cr III } Cluster | Zendy

Han Haitao | Zendy; Li Xiaolei | Zendy; Zhu Xiaofei | Zendy; Zhang Guoshuai | Zendy; Wang Shentang | Zendy; Hang Xinxin | Zendy; Tang Jinkui | Zendy; Liao Wuping | Zendy

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Single‐Molecule‐Magnet Behavior in a Calix[8]arene‐Capped {Tb 6 III Cr III } Cluster

Author(s) -

Han Haitao,

Li Xiaolei,

Zhu Xiaofei,

Zhang Guoshuai,

Wang Shentang,

Hang Xinxin,

Tang Jinkui,

Liao Wuping

Publication year - 2017

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201700013

Subject(s) - isostructural , chemistry , single molecule magnet , crystallography , cluster (spacecraft) , molecule , magnet , stereochemistry , magnetization , crystal structure , organic chemistry , magnetic field , physics , quantum mechanics , computer science , programming language

Four isostructural heptanuclear {(Ln 6 Cr)(C8A) 2 } compounds (Ln = Gd, Tb, Dy, and Tm; H 8 C8A = p‐tert ‐butylcalix[8]arene) were synthesized under solvothermal conditions. These four compounds feature a sandwich‐like unit in which the heterometallic {Ln III 6 Cr III } cluster is capped by two perpendicular calix[8]arene molecules in a double‐cone conformation. Magnetic investigations revealed that the {Tb III 6 Cr III } compound exhibits single‐molecule magnet (SMM) behavior.

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