( E )‐1,2‐Bis(3,5‐dinitro‐1 H ‐pyrazol‐4‐yl)diazene – Its 3D Potassium Metal–Organic Framework and Organic Salts with Super‐Heat‐Resistant Properties

( E )‐1,2‐Bis(3,5‐dinitro‐1 H ‐pyrazol‐4‐yl)diazene (H 2 NPA, 1 ) and its energetic salts, which are a series of new, energetic, highly heat‐resistant, dense explosives, were synthesized. The explosives contain four nitro groups and an azo‐bridged framework and were characterized by 1 H and 13 C NMR (in some cases 15 N NMR) spectroscopy, IR spectroscopy, and elemental analysis. The crystal structures of K 2 NPA (a three‐dimensional metal–organic framework, 3D MOF) and the guanidinium salt 4 were determined by single‐crystal X‐ray diffraction, and their properties (density, thermal stability, and sensitivity towards impact and friction) were investigated. The detonation properties were evaluated from the measured density and calculated heat of formation by the EXPLO5 v6.01 program. All of the salts exhibit thermal stabilities with decomposition temperatures ranging from 156 to 315 °C, high densities (1.70–2.15 g cm –3 ), high detonation velocities (8224–9083 m s –1 ), and high positive heats of formation (45.7–1040.1 kJ mol –1 ). The obtained 3D metal–organic framework explosive K 2 NPA combines exceptional thermal stability ( T d = 315 °C) with a high density ( d = 2.15 g cm –3 ) and possesses ideal calculated detonation velocity ( v D = 8275 m s –1 ) and pressure ( P CJ = 31.1 GPa) values. Moreover, its suitable impact sensitivity (IS) of 1.5 J and friction sensitivity (FS) of 60 N make K 2 NPA an outstanding, highly heat‐resistant, green primary explosive. The guanidinium salt 4 also exhibits a high thermal stability ( T d = 304 °C) that is superior to that of HMX, insensitivity to impact (IS > 40 J) and friction (FS > 360 N) comparable to those of 1,3,5‐triamino‐2,4,6‐trinitrobenzene (TATB), and a high detonation performance ( v D = 8391 m s –1 ).