Synthesis, Structure, and First Reactivity Studies of Functional (Phosphinoamino)boranes | Zendy

Majhi Paresh Kumar | Zendy; Franco José Manuel Villalba | Zendy; Schnakenburg Gregor | Zendy; Sasamori Takahiro | Zendy; Streubel Rainer | Zendy

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Synthesis, Structure, and First Reactivity Studies of Functional (Phosphinoamino)boranes

Author(s) -

Majhi Paresh Kumar,

Franco José Manuel Villalba,

Schnakenburg Gregor,

Sasamori Takahiro,

Streubel Rainer

Publication year - 2017

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201601366

Subject(s) - chemistry , boranes , microanalysis , nuclear magnetic resonance spectroscopy , reactivity (psychology) , chlorine , crystal structure , lithium (medication) , crystallography , density functional theory , single crystal , niobium , stereochemistry , inorganic chemistry , medicinal chemistry , organic chemistry , computational chemistry , boron , medicine , alternative medicine , pathology , endocrinology

Functional phosphanes having a P–N–B motif were obtained by treatment of chloro(organo)phosphanes with boryl amides. Compounds 4a – e are stable up to 100 °C and show no association in solution, even at low temperature (–70 °C). The functional phosphanes were characterized by NMR and IR spectroscopy, MS, and microanalysis, and phosphanes 4a , 4c , and 4e were additionally scrutinized by single‐crystal X‐ray crystallography. Preliminary studies on chlorine/lithium exchange of 4a led to anionic azaphosphaboriridine 5a′ .

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