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Synthesis and Characterization of the First Nickel(II)‐Centered Single‐Side Tris‐Functionalized Anderson‐Type Polyoxomolybdate
Author(s) -
Gumerova Nadiia I.,
Roller Alexander,
Rompel Annette
Publication year - 2016
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201601198
Subject(s) - chemistry , thermogravimetric analysis , tris , nickel , aqueous solution , ligand (biochemistry) , single crystal , crystallography , heteroatom , divalent , infrared spectroscopy , mass spectrometry , covalent bond , salt (chemistry) , inorganic chemistry , polymer chemistry , organic chemistry , ring (chemistry) , biochemistry , receptor , chromatography
The Ni‐centered Anderson‐type polyoxomolybdate [Ni(OH) 3 Mo 6 O 18 (OCH 2 ) 3 CNH 3 ] 3– was prepared in a two‐step aqueous reaction by covalent postfunctionalization of [Ni(OH) 6 Mo 6 O 18 ] 4– , isolated as its sodium Tris–NH 3 salt, and characterized by single‐crystal X‐ray diffraction, mass spectrometry, thermogravimetric analysis, and IR spectroscopy. The incorporation of a Tris–NH 2 ligand into the framework of a heteropolymolybdate bearing a divalent heteroatom, which resulted in the single‐sided product, was shown for the first time.