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Enhanced Photocatalytic Activity of a Molybdate‐Intercalated Iron‐Based Layered Double Hydroxide
Author(s) -
Mohapatra Lagnamayee,
Patra Dhananjaya,
Parida Kulamani,
Zaidi Syed Javaid
Publication year - 2017
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201601191
Subject(s) - chemistry , molybdate , photocatalysis , layered double hydroxides , hydroxide , intercalation (chemistry) , inorganic chemistry , coprecipitation , methyl orange , crystallinity , radical , photochemistry , photoluminescence , catalysis , crystallography , materials science , organic chemistry , optoelectronics
Herein, we report the design and successful fabrication of new Mg/Fe layered double hydroxides (LDHs) with different Mg/Fe molar ratios (2:1, 3:1, and 4:1) by a coprecipitation method. The prepared Mg/Fe (4:1) LDH sample with high crystallinity and phase purity was further modified by intercalation with molybdate anions. The structural, morphological, optical, electrochemical, and photocatalytic properties of the prepared catalysts were subsequently examined. In comparison with that of the Mg/Fe (4:1) LDH, the photocatalytic activity of the Mg/Fe (4:1) material with molybdate anions intercalated in the interlayer for the degradation of methyl orange (MO) was enhanced, and the processed followed apparent first‐order kinetics. Radical‐trapping experiments demonstrated that h + , OH · radicals, and O 2 – · radicals are the dominant reactive species for pollutant degradation. The highest photocatalytic activity of molybdate‐intercalated LDH is attributed mainly to the combined effects of its layered structure with Mg II –O–Fe III linkages and intercalated molybdate anions, which act as visible‐light absorption centers towards higher wavelengths and can promote charge‐carrier trapping as well as hinder the photogenerated electron–hole recombination. The time‐resolved photoluminescence (TRPL) spectra demonstrated the prolonged charge separation under visible light.