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Tin Sulfide Clusters with Polyheteroatomic Ligands: Syntheses, Structures, and Photoluminescence Properties
Author(s) -
Leusmann Eliza,
Rosemann Nils W.,
Weinert Bastian,
Chatterjee Sangam,
Dehnen Stefanie
Publication year - 2016
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201601143
Subject(s) - chemistry , heteroatom , tin , photoluminescence , cluster (spacecraft) , sulfide , ligand (biochemistry) , acetal , molecule , combinatorial chemistry , polymer chemistry , stereochemistry , organic chemistry , ring (chemistry) , biochemistry , physics , receptor , optics , programming language , computer science
2‐Hydrazinobenzothiazole and 2‐furaldehyde diethyl acetal were connected to complementarily functionalized tin sulfide clusters, with coupling of an acetal to a hydrazine‐functionalized cluster being so far without precedence. Neither ethers nor an N,S combination of heteroatoms has so far been present in the ligand shell of tetrelchalcogenide clusters. The resulting cluster molecules are based on inorganic [Sn 6 S 10 ] architectures and show different photoluminescence properties as a function of the attached ligands.