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Azaferrocene‐Based PNP‐Type Pincer Ligand: Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation
Author(s) -
Kuriyama Shogo,
Arashiba Kazuya,
Nakajima Kazunari,
Tanaka Hiromasa,
Yoshizawa Kazunari,
Nishibayashi Yoshiaki
Publication year - 2016
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201601051
Subject(s) - chemistry , pincer movement , molybdenum , chromium , reactivity (psychology) , stoichiometry , transition metal , catalysis , pincer ligand , ligand (biochemistry) , inorganic chemistry , nitrogen , nitrogen fixation , polymer chemistry , medicinal chemistry , organic chemistry , medicine , biochemistry , alternative medicine , receptor , pathology
A series of azaferrocene‐based PNP‐type pincer ligands were designed and prepared as new PNP‐type pincer ligands. Some transition‐metal complexes, including molybdenum, chromium, and iron complexes, bearing these azaferrocene‐based PNP‐type pincer ligands were also prepared and characterized by X‐ray analysis. The stoichiometric and catalytic reactivities of molybdenum–dinitrogen complexes toward nitrogen fixation were investigated in detail.