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A Rigid CNC Pincer Ligand Acting as a Tripodal Cp Analogue
Author(s) -
Jürgens Eva,
Kunz Doris
Publication year - 2017
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201601008
Subject(s) - chemistry , pincer movement , ligand (biochemistry) , pincer ligand , stereochemistry , fragment (logic) , crystal structure , crystallography , combinatorial chemistry , organic chemistry , receptor , catalysis , biochemistry , computer science , programming language
The unusual Cp‐like behavior of an anionic bis(NHC)carbazolide pincer ligand coordinating to a Cp*Ru fragment in a facial mode is presented. The unexpected facial coordination is demonstrated by single‐crystal X‐ray structure analysis.