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A Silacyclopropene with a Six‐Coordinate Silicon Atom and an SiN 4 C 2 Skeleton: Synthesis and Structural Characterization
Author(s) -
Baus Johannes A.,
Laskowski Nadine,
Tacke Reinhold
Publication year - 2016
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201600982
Subject(s) - chemistry , characterization (materials science) , silicon , atom (system on chip) , skeleton (computer programming) , crystallography , nanotechnology , stereochemistry , organic chemistry , materials science , computer science , embedded system , programming language
Treatment of the donor‐stabilized silylene [ i PrNC(Ph)N i Pr] 2 Si with Ph–C≡C–Ph resulted in a [2+1] cycloaddition reaction to afford a silicon(IV) compound, the first silacyclopropene with a six‐coordinate silicon atom. This compound was structurally characterized by single‐crystal X‐ray diffraction and multinuclear NMR spectroscopic studies in the solid state and in solution.