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Group 11 Metal Complexes with Unsymmetrical Bifunctional Ferrocene Ligands
Author(s) -
Shi YuJun,
Laguna Antonio,
Villacampa M. Dolores,
Gimeno M. Concepción
Publication year - 2017
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201600929
Subject(s) - chemistry , ferrocene , ligand (biochemistry) , bifunctional , metal , copper , phosphorus , medicinal chemistry , inorganic chemistry , polymer chemistry , crystallography , stereochemistry , organic chemistry , catalysis , electrochemistry , biochemistry , receptor , electrode
The reactions of two unsymmetrical P ^ N ( L1 ) and P ^ P ( L2 ) ferrocene (Fc) ligands towards group 11 metal complexes were studied. Ligand L1 shows different behavior with the three metals. Gold forms mononuclear derivatives with the metal center coordinated to the phosphorus atom, whereas the reactions with silver(I) or copper(I) complexes afford mononuclear or dinuclear compounds in which both donor atoms, phosphorus and nitrogen, are involved in the coordination to the metal center. The reactions of the diphosphine ligand [Fc(CH 2 PPh 2 )(PPh 2 )] ( L2 ) with gold(I), gold(III), silver(I), or copper(I) complexes afford mono‐, di‐, or trinuclear derivatives. Some homo‐ and heterodinuclear compounds were obtained through the reactions of the mononuclear gold(III) complex [Au(C 6 F 5 ) 3 {Fc(CH 2 PPh 2 )(PPh 2 )}] ( 6 ), in which one of the phosphorus atoms is free, with gold(I), gold(III), and silver(I) deriiivatives. Some of these derivatives were characterized by X‐ray diffraction analysis.