Silylene‐Induced Reduction of [Mn 2 (CO) 10 ]: Formation of a Five‐Coordinate Silicon(IV) Complex with an O‐Bound [(OC) 4 Mn=Mn(CO) 4 ] 2–  Ligand | Zendy

Baus Johannes A. | Zendy; Poater Jordi | Zendy; Bickelhaupt F. Matthias | Zendy; Tacke Reinhold | Zendy

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Silylene‐Induced Reduction of [Mn 2 (CO) 10 ]: Formation of a Five‐Coordinate Silicon(IV) Complex with an O‐Bound [(OC) 4 Mn=Mn(CO) 4 ] 2– Ligand

Author(s) -

Baus Johannes A.,

Poater Jordi,

Bickelhaupt F. Matthias,

Tacke Reinhold

Publication year - 2017

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201600913

Subject(s) - silylene , chemistry , silicon , redox , moiety , manganese , crystallography , molecule , stereochemistry , inorganic chemistry , organic chemistry

Treatment of the donor‐stabilized silylene [ i PrNC(N i Pr 2 )N i Pr] 2 Si ( 1 ) with [Mn 2 (CO) 10 ] leads to the five‐coordinate silicon(IV) complex 6 , accompanied by elimination of two CO molecules. In this redox reaction, the dimanganese fragment is reduced to form an [(OC) 4 Mn=Mn(CO) 4 ] 2– moiety that is coordinated to the silicon(IV) species {[ i PrNC(N i Pr 2 )N i Pr] 2 Si} 2+ .

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