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Reactivity Studies of Metal–Organic Frameworks under Vapor‐Assisted Aging: Structural Interconversions and Transformations
Author(s) -
Tang Panjuan,
Jia Chunmei,
Jiang Yujie,
Gong Wei,
Cao Xiaocong,
Yang Junyi,
Yuan Wenbing
Publication year - 2016
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201600907
Subject(s) - chemistry , microporous material , reactivity (psychology) , metal organic framework , solvent , metal , nanotechnology , organic chemistry , materials science , adsorption , medicine , alternative medicine , pathology
We systematically studied the chemical reactivities of 13 metal–organic frameworks (MOFs) under vapor‐assisted aging (VAG) at room temperature. The MOFs aged in solvent vapor at room temperature showed unexpectedly high reactivities for transformations into structures with other coordination networks. In addition, three MOFs reacted with 4,4′‐bipyridine to form three‐dimensional microporous MOFs under VAG conditions at room temperature.