First Evidence of a Water‐Soluble Plutonium(IV) Hexanuclear Cluster | Zendy

Tamain Christelle | Zendy; Dumas Thomas | Zendy; Guillaumont Dominique | Zendy; Hennig Christoph | Zendy; Guilbaud Philippe | Zendy

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First Evidence of a Water‐Soluble Plutonium(IV) Hexanuclear Cluster

Author(s) -

Tamain Christelle,

Dumas Thomas,

Guillaumont Dominique,

Hennig Christoph,

Guilbaud Philippe

Publication year - 2016

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201600656

Subject(s) - chemistry , plutonium , cluster (spacecraft) , dota , solubility , solid state , genetic algorithm , spectroscopy , absorption (acoustics) , oxidation state , radiochemistry , nuclear chemistry , inorganic chemistry , crystallography , chelation , metal , organic chemistry , evolutionary biology , computer science , acoustics , biology , programming language , physics , quantum mechanics

The singular Pu IV hexanuclear cluster [Pu 6 (OH) 4 O 4 ] 12+ stabilized by 1,4,7,10‐tetraazacyclododecane‐1,4,7,10‐tetraacetic acid (DOTA) ligands was structurally characterized for the first time both in the solid state and in water solution by using X‐ray diffraction and X‐ray absorption and UV/Vis spectroscopy. The stability of this cluster in water and its high solubility over a large pH range are of upmost importance for plutonium environmental speciation with potential applications in a related migration model.

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