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Rational Synthesis of the Carbonyl(perthiolato)diiron [Fe2(S3CPh2)(CO)6] and Related Complexes
Author(s) -
Zhao Peihua,
Gray Danielle L.,
Rauchfuss Thomas B.
Publication year - 2016
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201600366
Subject(s) - chemistry , yield (engineering) , ligand (biochemistry) , flue gas desulfurization , medicinal chemistry , stereochemistry , inorganic chemistry , organic chemistry , biochemistry , materials science , receptor , metallurgy
The photochemical reaction of Fe 2 (S 2 )(CO) 6 and Ph 2 CS affords the perthiolate Fe 2 (S 3 CPh 2 )(CO) 6 ( 1 ) in good yield. As confirmed crystallographically, 1 contains a previously elusive perthiolate ligand. The related reaction of Fe 2 (S 2 )(CO) 5 (PPh 3 ) and Ph 2 CS gave Fe 2 (S 3 CPh 2 )(CO) 5 (PPh 3 ). Although Fe 3 S 2 (CO) 9 and Ph 2 CS failed to efficiently give Fe 2 (S 2 CPh 2 )(CO) 6 , this compound could be prepared by desulfurization of 1 using PPh 3 .
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