Helical CuICuII3 Metallocavitands with Sulfur‐Containing Schiff Base Ligands Exhibiting Ferromagnetic or Antiferromagnetic Interactions | Zendy

IgashiraKamiyama Asako | Zendy; Saito Masayuki | Zendy; Kodera Shuntaro | Zendy; Konno Takumi | Zendy

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Helical CuICuII3 Metallocavitands with Sulfur‐Containing Schiff Base Ligands Exhibiting Ferromagnetic or Antiferromagnetic Interactions

Author(s) -

IgashiraKamiyama Asako,

Saito Masayuki,

Kodera Shuntaro,

Konno Takumi

Publication year - 2016

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201600290

Subject(s) - chemistry , antiferromagnetism , sulfur , schiff base , substituent , crystallography , ferromagnetism , ion , copper , stereochemistry , inorganic chemistry , organic chemistry , condensed matter physics , physics

A unique example of self‐assembly of chiral sulfur‐containing Schiff base ligands (SBLs) into a mixed‐valent metallocavitand is reported. A tetranuclear complex with one Cu I and three Cu II ions bridged by three sulfur‐containing SBLs was obtained, in which connected Cu II NO 2 S and Cu I S 3 planes form a Cu I Cu II 3 metallocavitand hosting a trialkylammonium cation in its chiral cavity. The ferro‐ or antiferromagnetic interactions in the complexes can be tuned by changing a substituent on the SBL.

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