Premium
A Three‐Dimensional Tetraphenylíethene‐Based Metal–Organic Framework for Selective Gas Separation and Luminescence Sensing of Metal Ions
Author(s) -
Yang Wei,
Chang Ganggang,
Wang Hailong,
Hu TongLiang,
Yao Zizhu,
Alfooty Khalid,
Xiang Shengchang,
Chen Banglin
Publication year - 2016
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201600201
Subject(s) - chemistry , luminescence , metal organic framework , metal , metal ions in aqueous solution , biphenyl , ion , porosity , ligand (biochemistry) , inorganic chemistry , cadmium , photochemistry , organic chemistry , adsorption , physics , biochemistry , receptor , optoelectronics
A three‐dimensional porous metal–organic framework (MOF), UTSA‐86, made up of cadmium ions and a chromophoric tetraphenylethene‐based tetracarboxylate ligand, 4′,4′′′,4,4‐(ethene‐1,1,2,2‐tetrayl)tetrakis(1,1′‐biphenyl‐4‐carboxylic acid (H 4 ettc), has been synthesized and characterized by single‐crystal X‐ray diffraction analysis. This multifunctional MOF exhibits permanent porosity, selective gas uptake, and luminescence sensing of metal ions.