Ni(bpy)(cod): A Convenient Entryway into the Efficient Hydroboration of Ketones, Aldehydes, and Imines | Zendy

King Amanda E. | Zendy; Stieber S. Chantal E. | Zendy; Henson Neil J. | Zendy; Kozimor Stosh A. | Zendy; Scott Brian L. | Zendy; Smythe Nathan C. | Zendy; Sutton Andrew D. | Zendy; Gordon John C. | Zendy

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Ni(bpy)(cod): A Convenient Entryway into the Efficient Hydroboration of Ketones, Aldehydes, and Imines

Author(s) -

King Amanda E.,

Stieber S. Chantal E.,

Henson Neil J.,

Kozimor Stosh A.,

Scott Brian L.,

Smythe Nathan C.,

Sutton Andrew D.,

Gordon John C.

Publication year - 2016

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201600143

Subject(s) - chemistry , hydroboration , borane , catalysis , adduct , pinacol , benzene , medicinal chemistry , ligand (biochemistry) , ketone , organic chemistry , biochemistry , receptor

The catalytic hydroboration of ketones, aldehydes, and imines with pinacol borane and Ni(bpy)(cod) has been demonstrated in benzene at room temperature and low catalyst loadings (0.03–0.3 mol‐%). Spectroscopic and structural evidence support the formulation of Ni(bpy)(cod) as containing a Ni I cation and a bpy · – ligand. The Ni(bpy)(cod) complex reacts quickly with ketonic substrates to form an adduct that appears to function as an entryway into catalytic activity.

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