SALE‐Ing a MOF‐Based “Ship of Theseus.” Sequential Building‐Block Replacement for Complete Reformulation of a Pillared‐Paddlewheel Metal‐Organic Framework | Zendy

Xu Yan | Zendy; Vermeulen Nicolaas A. | Zendy; Liu Yangyang | Zendy; Hupp Joseph T. | Zendy; Farha Omar K. | Zendy

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SALE‐Ing a MOF‐Based “Ship of Theseus.” Sequential Building‐Block Replacement for Complete Reformulation of a Pillared‐Paddlewheel Metal‐Organic Framework

Author(s) -

Xu Yan,

Vermeulen Nicolaas A.,

Liu Yangyang,

Hupp Joseph T.,

Farha Omar K.

Publication year - 2016

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201600069

Subject(s) - transmetalation , chemistry , metal organic framework , block (permutation group theory) , nickel , node (physics) , unit (ring theory) , organic chemistry , catalysis , adsorption , geometry , mathematics , mathematics education , structural engineering , engineering

A complete structure and composition evolution of a pillared‐paddlewheel metal‐organic framework was achieved using a combination of solvent‐assisted linker exchange (SALE) and node transmetalation. In this example, each building unit – the di‐topic carboxylate strut, the di‐topic nitrogen‐based pillar, and the di‐zinc node – of the original metal‐organic framework is replaced in sequential fashion to produce a nickel‐based daughter metal‐organic framework with entirely different components.

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