Gold‐Mediated Isomerization of Cyclooctyne to Ring Fused Olefinic Bicycles | Zendy

Das Animesh | Zendy; Hua Yuanda | Zendy; Yousufuddin Muhammed | Zendy; Cundari Thomas R. | Zendy; Jeon Junha | Zendy; Dias H. V. Rasika | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Gold‐Mediated Isomerization of Cyclooctyne to Ring Fused Olefinic Bicycles

Author(s) -

Das Animesh,

Hua Yuanda,

Yousufuddin Muhammed,

Cundari Thomas R.,

Jeon Junha,

Dias H. V. Rasika

Publication year - 2016

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201600021

Subject(s) - isomerization , chemistry , alkyne , bicyclic molecule , carbene , cationic polymerization , ring (chemistry) , stereochemistry , photochemistry , organic chemistry , catalysis

Isomerization reactions of cyclooctyne mediated by N‐heterocyclic carbene supported gold(I) leading to ring‐contraction and the formation of 5/5‐fused bicyclic alkenes have been observed. Isolation and complete characterization, including X‐ray structural data of the cationic gold(I) complexes featuring the precursor alkyne and the product alkenes are also described.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research