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Hydrogen Photoevolution from a Green‐Absorbing Iridium(III)–Cobalt(III) Dyad
Author(s) -
Jacques Alexandre,
Schott Olivier,
Robeyns Koen,
Hanan Garry S.,
Elias Benjamin
Publication year - 2016
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201501467
Subject(s) - chemistry , iridium , supramolecular chemistry , cobalt , photochemistry , photocatalysis , hydrogen , electron transfer , denticity , ligand (biochemistry) , inorganic chemistry , crystallography , catalysis , organic chemistry , receptor , crystal structure , biochemistry
A bis‐cyclometaling ligand afforded a novel Ir III –Co III dinuclear complex with vectorial electron transfer that evolved hydrogen gas upon yellow‐light irradiation. The supramolecular photosystem provided increased stability during photocatalysis with respect to that of classic bidentate systems.