Functionalized 1′‐Substituted Iodoferrocenes and Their Pd‐Catalyzed Heck Cross‐Coupling Reactions | Zendy

Roemer Max | Zendy; Donnadieu Bruno | Zendy; Nijhuis Christian A. | Zendy

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Functionalized 1′‐Substituted Iodoferrocenes and Their Pd‐Catalyzed Heck Cross‐Coupling Reactions

Author(s) -

Roemer Max,

Donnadieu Bruno,

Nijhuis Christian A.

Publication year - 2016

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201501451

Subject(s) - chemistry , moiety , heck reaction , electrophile , ferrocene , catalysis , palladium , combinatorial chemistry , coupling reaction , coupling (piping) , organic chemistry , medicinal chemistry , electrochemistry , mechanical engineering , engineering , electrode

This paper describes the preparation of a variety of 1′‐substituted iodoferrocenes from 1‐iodo‐1′‐(tri‐ n ‐butyltin)ferrocene by an electrophilic substitution of the tri‐ n ‐butyltin moiety with functionalized acylium and benzoylium species. Additionally, we demonstrate a Heck coupling protocol for these functionalized iodoferrocenes with ethenylferrocene.

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