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Functionalized 1′‐Substituted Iodoferrocenes and Their Pd‐Catalyzed Heck Cross‐Coupling Reactions
Author(s) -
Roemer Max,
Donnadieu Bruno,
Nijhuis Christian A.
Publication year - 2016
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201501451
Subject(s) - chemistry , moiety , heck reaction , electrophile , ferrocene , catalysis , palladium , combinatorial chemistry , coupling reaction , coupling (piping) , organic chemistry , medicinal chemistry , electrochemistry , mechanical engineering , engineering , electrode
This paper describes the preparation of a variety of 1′‐substituted iodoferrocenes from 1‐iodo‐1′‐(tri‐ n ‐butyltin)ferrocene by an electrophilic substitution of the tri‐ n ‐butyltin moiety with functionalized acylium and benzoylium species. Additionally, we demonstrate a Heck coupling protocol for these functionalized iodoferrocenes with ethenylferrocene.