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Synthesis of Cu 2 O@Ag Polyhedral Core–Shell Nanoparticles by a Thermal Decomposition Approach for Catalytic Applications
Author(s) -
Kandula Syam,
Jeevanandam Pethaiyan
Publication year - 2016
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201501389
Subject(s) - nanoparticle , chemistry , catalysis , thermal decomposition , octahedron , aqueous solution , diffuse reflectance infrared fourier transform , surface plasmon resonance , transmission electron microscopy , silver nanoparticle , scanning electron microscope , crystallography , analytical chemistry (journal) , nanotechnology , materials science , crystal structure , photocatalysis , organic chemistry , composite material
Cu 2 O@Ag polyhedral core–shell nanoparticles with different morphologies (rhombicuboctahedral, cuboctahedral, truncated octahedral, and octahedral) have been successfully synthesized by a thermal decomposition approach. The Cu 2 O@Ag polyhedral core–shell nanoparticles were characterized by X‐ray diffraction, electron microscopy, surface‐area analysis, and diffuse reflectance spectroscopy. The XRD results confirm the presence of Cu 2 O and silver in the Cu 2 O@Ag samples. Electron microscopy studies prove the formation of a shell of silver nanoparticles on the polyhedral Cu 2 O microcrystals. The diffuse reflectance spectra of the Cu 2 O@Ag polyhedral core–shell nanoparticles show band‐gap absorption owing to Cu 2 O as well as surface plasmon resonance owing to silver nanoparticles. The catalytic activities of the Cu 2 O@Ag polyhedral core–shell nanoparticles were explored for the reductions of 4‐nitrophenol and methylene blue in aqueous solutions. The Cu 2 O@Ag core–shell nanoparticles with octahedral morphology show higher catalytic activity than the other Cu 2 O@Ag samples. The core–shell nanoparticles show a higher turnover frequency (TOF) and activity parameter ( k act ) for 4‐nitrophenol reduction and a higher apparent rate constant ( k app ) for methylene blue reduction compared to the previously reported values. The reusability of the Cu 2 O@Ag polyhedral core–shell nanoparticles was also tested, and they show stability for up to five cycles without loss of efficiency.