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Scorpionates of the “Tetrahedral Enforcer” Variety as Ancillary Ligands for Dinitrogen Complexes of First Row Transition Metals (Cr–Co)
Author(s) -
Cummins Daniel C.,
Yap Glenn P. A.,
Theopold Klaus H.
Publication year - 2016
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201501326
Subject(s) - chemistry , transition metal , reactivity (psychology) , boron , molecule , medicinal chemistry , tetrahedron , stereochemistry , crystallography , inorganic chemistry , catalysis , organic chemistry , medicine , alternative medicine , pathology
Dinitrogen complexes of the first row transition metals Cr–Co supported by 2 nd generation hydrotris(pyrazolyl)borate (Tp R,R′ ) ligands were characterized by structure and reactivity. Compounds of the type (Tp R,R′ M) n (N 2 ) ( n = 1,2) were prepared and evaluated as precursors for small molecule activation, with specific application to reactions of O 2 .