Scorpionates of the “Tetrahedral Enforcer” Variety as Ancillary Ligands for Dinitrogen Complexes of First Row Transition Metals (Cr–Co) | Zendy

Cummins Daniel C. | Zendy; Yap Glenn P. A. | Zendy; Theopold Klaus H. | Zendy

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Scorpionates of the “Tetrahedral Enforcer” Variety as Ancillary Ligands for Dinitrogen Complexes of First Row Transition Metals (Cr–Co)

Author(s) -

Cummins Daniel C.,

Yap Glenn P. A.,

Theopold Klaus H.

Publication year - 2016

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201501326

Subject(s) - chemistry , transition metal , reactivity (psychology) , boron , molecule , medicinal chemistry , tetrahedron , stereochemistry , crystallography , inorganic chemistry , catalysis , organic chemistry , medicine , alternative medicine , pathology

Dinitrogen complexes of the first row transition metals Cr–Co supported by 2 nd generation hydrotris(pyrazolyl)borate (Tp R,R′ ) ligands were characterized by structure and reactivity. Compounds of the type (Tp R,R′ M) n (N 2 ) ( n = 1,2) were prepared and evaluated as precursors for small molecule activation, with specific application to reactions of O 2 .

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