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Fluorescence Quenching in BODIPYs Having Ir‐ and Rh‐Tethered Complexes
Author(s) -
Chu Gong M.,
Fernández Israel,
GuerreroMartínez Andrés,
Ramírez de Arellano Carmen,
Sierra Miguel A.
Publication year - 2016
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201501283
Subject(s) - bodipy , chemistry , photochemistry , chromophore , fluorescence , moiety , photoinduced electron transfer , quenching (fluorescence) , metal , electron transfer , stereochemistry , organic chemistry , physics , quantum mechanics
The effect of Rh‐ and Ir‐centers on the optical properties of the BODIPY core has been studied. To this end, novel metal complexes tethered to BODIPY have been prepared through an easy and versatile procedure using N‐directed C–H activation reactions. The organometallic moiety has a tremendous influence on the emissive properties of the BODIPY fragment. A photoinduced electron transfer (PET) mechanism is suggested to be the main mechanism responsible for the suppression of the BODIPY fluorescence emission in the newly formed dyads. The efficiency of the PET depends on both the distance between the chromophores in the dyad and the nature of the transition metal (Rh vs. Ir).