BH 4  – ‐Promoted, Radical‐Initiated, Catalytic Oxidation of (CH 3 ) 2 SO by N 2 O in Aqueous Solution | Zendy

Yanus Rinat Levy | Zendy; Yardeni Guy | Zendy; Maimon Eric | Zendy; Saphier Magal | Zendy; Zilbermann Israel | Zendy; Meyerstein Dan | Zendy

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BH 4 – ‐Promoted, Radical‐Initiated, Catalytic Oxidation of (CH 3 ) 2 SO by N 2 O in Aqueous Solution

Author(s) -

Yanus Rinat Levy,

Yardeni Guy,

Maimon Eric,

Saphier Magal,

Zilbermann Israel,

Meyerstein Dan

Publication year - 2016

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201501264

Subject(s) - radical , chemistry , catalysis , aqueous solution , chain reaction , photochemistry , oxidation process , reaction intermediate , inorganic chemistry , medicinal chemistry , organic chemistry , pulp and paper industry , engineering

Methyl radicals react with BH 4 – to form BH 3 · – /BH 4 · ( k ≈ 5 × 10 3 M –1 s –1 . BH 3 · – /BH 4 · reacts with N 2 O to form OH · radicals, which react with (CH 3 ) 2 SO to form methyl radicals and thus initiate a chain oxidation process. It is suggested that analogous reactions can be initiated by the reaction of OH · radicals with other organic substrates. Thus, BH 4 – promotes oxidation processes.

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