Bad‐Metal‐Layered Sulfide Oxide CsV 2 S 2 O | Zendy

Valldor Martin | Zendy; Merz Patrick | Zendy; Prots Yurii | Zendy; Schnelle Walter | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Bad‐Metal‐Layered Sulfide Oxide CsV 2 S 2 O

Author(s) -

Valldor Martin,

Merz Patrick,

Prots Yurii,

Schnelle Walter

Publication year - 2016

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201501154

Subject(s) - chemistry , tetragonal crystal system , oxide , metal , stoichiometry , crystallite , paramagnetism , crystallography , electrical resistivity and conductivity , sulfide , crystal structure , inorganic chemistry , analytical chemistry (journal) , mineralogy , condensed matter physics , physics , organic chemistry , engineering , chromatography , electrical engineering

Through a solid‐state reaction between stoichiometric amounts of a mixed cesium oxide Cs 2 O 1.3 , VS, S, and V 2 O 5 , a polycrystalline powder of CsV 2 S 2 O was obtained. Small single crystals could be grown in a CsCl melt by allowing Cs 2 SO 4 , V metal and S powders to react. The crystals have a plate‐like morphology, consistent with the tetragonal crystal‐structure symmetry [ P 4/ mmm , a = 3.9455(1), c = 7.4785(1) Å]. Magnetic measurements suggest that CsV 2 S 2 O is a temperature‐independent paramagnet, and resistivity data concur with a bad metal. The mixed oxidation state of V on one crystallographic site offers a tentative explanation of the electronic properties of the title compound.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research