Premium
Synthesis and Structures of Ti‐Pd Heterobimetallic Complexes
Author(s) -
Suzuki Noriyuki,
Haraga Kenji,
Shimamura Tatsuki,
Masuyama Yoshiro
Publication year - 2015
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201501003
Subject(s) - moiety , chemistry , denticity , bimetallic strip , palladium , benzonitrile , titanium , medicinal chemistry , nuclear magnetic resonance spectroscopy , chloride , stereochemistry , polymer chemistry , crystallography , catalysis , organic chemistry , crystal structure
Heterobimetallic complexes containing titanium and palladium were prepared from O , N , O – N , N multidentate ligands. The ligands each contained an O , N , O ‐tridentate part based on a 2,6‐lutidine scaffold and an N , N ‐bidentate di(pyridin‐2‐yl) part. The O , N , O ‐moiety selectively coordinated to a titanium atom on treatment with titanium(tetraisopropoxide), although one of the di(pyridin‐2‐yl) groups in the N , N ‐moiety coordinated to the titanium atom. The N , N ‐bidentate di(pyridin‐2‐yl) moiety coordinated to the palladium atom on treatment with bis(benzonitrile)palladium(II) chloride to afford a heterobimetallic complex. The dynamic behavior of the complexes in solution was studied by NMR spectroscopy.