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Selenium‐Substituted Phosphaalkenes Obtained through 1,2‐Elimination of Chlorosilanes from Selenenylchlorophosphines
Author(s) -
Sasamori Takahiro,
Villalba Franco José Manuel,
Guo JingDong,
Sugamata Koh,
Nagase Shigeru,
Streubel Rainer,
Tokitoh Norihiro
Publication year - 2016
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201500989
Subject(s) - chemistry , chlorosilane , lewis acids and bases , selenium , mechanism (biology) , intramolecular force , medicinal chemistry , computational chemistry , stereochemistry , organic chemistry , silicon , catalysis , philosophy , epistemology
Stable selenenyl‐chlorophosphines, bearing a silylalkyl group, were synthesized. Subsequent treatment with Lewis acids such as AlCl 3 afforded the corresponding phosphaalkenes. A reaction mechanism that proceeds through an intramolecular 1,2‐elimination of chlorosilane was proposed.