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Group 8 Metallomacrocycles – Synthesis, Characterization, and Stability
Author(s) -
Ludlow James M.,
Guo Zaihong,
Schultz Anthony,
Sarkar Rajarshi,
Moorefield Charles N.,
Wesdemiotis Chrys,
Newkome George R.
Publication year - 2015
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201500971
Subject(s) - chemistry , homoleptic , tandem , ruthenium , characterization (materials science) , spectroscopy , nuclear magnetic resonance spectroscopy , mass spectrometry , luminescence , stereochemistry , metal , nanotechnology , organic chemistry , catalysis , materials science , physics , chromatography , quantum mechanics , composite material , optoelectronics
The one‐step synthesis of the first homoleptic metallomacrocycle is reported. Characterization of the Os II complex, along with its Fe II and Ru II analogues, was accomplished by NMR spectroscopy, ESI‐MS, TWIM‐MS, gradient tandem‐MS, CV, luminescence and UV/Vis spectroscopy. Center‐of‐mass collision energies, derived from gradient tandem‐MS, reveal that the ‐based structures are more stable than those of .