Formation of a Carbene–Phosphinidene Adduct by NHC‐Induced P–P Bond Cleavage in Sodium Tetramesityltetraphosphanediide | Zendy

Adhikari Anup K. | Zendy; Grell Toni | Zendy; Lönnecke Peter | Zendy; HeyHawkins Evamarie | Zendy

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Formation of a Carbene–Phosphinidene Adduct by NHC‐Induced P–P Bond Cleavage in Sodium Tetramesityltetraphosphanediide

Author(s) -

Adhikari Anup K.,

Grell Toni,

Lönnecke Peter,

HeyHawkins Evamarie

Publication year - 2016

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201500952

Subject(s) - phosphinidene , chemistry , carbene , adduct , cleavage (geology) , iodide , bond cleavage , medicinal chemistry , sodium iodide , nuclear magnetic resonance spectroscopy , mass spectrometry , stereochemistry , photochemistry , crystallography , organic chemistry , catalysis , engineering , geotechnical engineering , chromatography , fracture (geology)

The reaction of [Na 2 (thf) 4 P 4 Mes 4 ] ( 1 ) (Mes = 2,4,6‐Me 3 C 6 H 2 ) with 1,3‐dimethylimidazolin‐2‐ylidene (Me 2 Im) or the corresponding imidazolium iodide ([Me 2 ImH]I) leads to P–P bond cleavage and formation of the carbene–phosphinidene adduct (Me 2 Im)PMes ( 2 ), which was characterized by NMR spectroscopy, mass spectrometry, and X‐ray crystallography.

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