Cu 3 (SeO 4 ) 2 (SeO 3 OH) 2 (H 2 O) 16  – The First Example of a Linear Octahedral–Tetrahedral Heptamer in Inorganic Compounds | Zendy

Gurzhiy Vladislav V. | Zendy; AlShuray Alexander | Zendy; Britvin Sergey N. | Zendy; Krivovichev Sergey V. | Zendy

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Cu 3 (SeO 4 ) 2 (SeO 3 OH) 2 (H 2 O) 16 – The First Example of a Linear Octahedral–Tetrahedral Heptamer in Inorganic Compounds

Author(s) -

Gurzhiy Vladislav V.,

AlShuray Alexander,

Britvin Sergey N.,

Krivovichev Sergey V.

Publication year - 2015

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201500927

Subject(s) - octahedron , tetrahedron , crystallography , chemistry , copper , hydrate , jahn–teller effect , crystal structure , ion , organic chemistry

Cu 3 (SeO 4 ) 2 (SeO 3 OH) 2 (H 2 O) 16 ( 1 ) is a novel copper selenate hydrate and the first inorganic compound to contain linear octahedral–tetrahedral heptamers. The heptamers are formed by successive polymerization of two SeO 3 OH tetrahedra, two SeO 4 tetrahedra, and three Cu(H 2 O) 4 O 2 octahedra. The linkages between the octahedra and tetrahedra are in the trans ‐configuration, which is in agreement with the Jahn–Teller distortion of the octahedral coordination geometry of Cu 2+ .

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