Synthesis and Characterization of a Triphos Ligand Derivative and the Corresponding Pd II  Complexes | Zendy

Miller Deanna L. | Zendy; Boro Brian J. | Zendy; Grubel Katarzyna | Zendy; Helm Monte L. | Zendy; Appel Aaron M. | Zendy

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Synthesis and Characterization of a Triphos Ligand Derivative and the Corresponding Pd II Complexes

Author(s) -

Miller Deanna L.,

Boro Brian J.,

Grubel Katarzyna,

Helm Monte L.,

Appel Aaron M.

Publication year - 2015

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201500791

Subject(s) - chemistry , trifluoromethanesulfonate , ligand (biochemistry) , phosphine , triphos , medicinal chemistry , derivative (finance) , chloride , hydroxymethyl , stereochemistry , catalysis , organic chemistry , biochemistry , receptor , financial economics , economics

The synthesis of the new bis[2‐(diphenylphosphino)ethyl](hydroxymethyl)phosphine tridentate ligand L CH2OH/Ph is reported. The ligand reacts with [Pd(Cl) 2 (PhCN) 2 ] to form [Pd(L CH2OH/Ph )Cl]Cl. Exchange of the chloride ions for triflate (OTf – ) using AgOTf yielded pure [Pd(L CH2OH/Ph )OTf]OTf. In addition to spectral characterization, the free ligand, L CH2OH/Ph , and the Pd II complex, [Pd(L CH2OH/Ph )OTf]OTf, were structurally characterized.

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