On the Role of Chalcogen Donor Atoms in Diimine‐Dichalcogenolate Pt II  SONLO Chromophores: Is It Worth Replacing Sulfur with Selenium? | Zendy

Pintus Anna | Zendy; Aragoni M. Carla | Zendy; Isaia Francesco | Zendy; Lippolis Vito | Zendy; Lorcy Dominique | Zendy; Slawin Alexandra M. Z. | Zendy; Woollins J. Derek | Zendy; Arca Massimiliano | Zendy

Premium

On the Role of Chalcogen Donor Atoms in Diimine‐Dichalcogenolate Pt II SONLO Chromophores: Is It Worth Replacing Sulfur with Selenium?

Author(s) -

Pintus Anna,

Aragoni M. Carla,

Isaia Francesco,

Lippolis Vito,

Lorcy Dominique,

Slawin Alexandra M. Z.,

Woollins J. Derek,

Arca Massimiliano

Publication year - 2015

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201500777

Subject(s) - chalcogen , chemistry , diimine , selenium , sulfur , chromophore , electrochemistry , inorganic chemistry , photochemistry , crystallography , electrode , catalysis , organic chemistry

Two new diimine‐diselenolate Pt II chromophores [Pt(bipy)(Me‐dset)] ( 1 ) and [Pt(phen)(Me‐dset)] ( 2 ) (Me‐dset 2– = N ‐methyl‐2‐thioxothiazoline‐4,5‐diselenolate) were synthesized and characterized. The effect of replacing sulfur with selenium was investigated by comparing the UV/Vis spectroscopic and electrochemical properties of 1 and 2 with those of the corresponding sulfur analogues, [Pt(bipy)(Me‐dmet)] ( 3 ) and [Pt(phen)(Me‐dmet)] ( 4 ), with a particular focus on their linear and nonlinear optical properties.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research