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Ruthenium(II) and Iridium(III) Complexes Bearing Phosphinepyridonate and Phosphinequinolinolate Chelates
Author(s) -
Jiang Fan,
Achard Mathieu,
Roisnel Thierry,
Dorcet Vincent,
Bruneau Christian
Publication year - 2015
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201500765
Subject(s) - ruthenium , iridium , chelation , chemistry , polymer chemistry , combinatorial chemistry , inorganic chemistry , catalysis , organic chemistry
Straightforward preparation of five‐membered P,N and P,O prochelates was easily achieved from 6‐methyl‐2‐pyridinol and 2‐quinolinol. From these ligands, access to the corresponding well‐defined ruthenium(II) and iridium(III) complexes was investigated. Owing to the hemilability as well as the reversible proton‐responsive character of these chelates, the resulting well‐defined ruthenium complexes exhibit interesting activities in hydrogenation.