A Complex Self‐Catenated Coordination Framework with a Rare (3,12)‐Connected Underlying Net Showing Selective Adsorption of CO 2 | Zendy

Luo Feng | Zendy; Meng Pan Pan | Zendy; Feng Xue Feng | Zendy; Dang Li Long | Zendy; Zhang Xiao Jing | Zendy

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A Complex Self‐Catenated Coordination Framework with a Rare (3,12)‐Connected Underlying Net Showing Selective Adsorption of CO 2

Author(s) -

Luo Feng,

Meng Pan Pan,

Feng Xue Feng,

Dang Li Long,

Zhang Xiao Jing

Publication year - 2015

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201500715

Subject(s) - chemistry , metal organic framework , adsorption , dumbbell , selectivity , kinetic energy , topology (electrical circuits) , crystallography , organic chemistry , catalysis , medicine , mathematics , combinatorics , physical therapy , physics , quantum mechanics

Herein, we report a unique self‐catenated metal‐organic framework (MOF) with an underlying (3,12)‐connected topology based on Co 4 clusters. Moreover, the special dumbbell‐like pore configuration, the exact match between the pore aperture and the kinetic diameter of CO 2 , as well as the coexistence of acylamide and NH 2 groups in the MOF enhances the selectivity of adsorption of CO 2 over other gases such as CO, CH 4 , O 2 , and N 2 .

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