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Facile Synthesis of Bimodal Mesoporous Fe 3 O 4 @SiO 2 Composite for Efficient Removal of Methylene Blue
Author(s) -
Tan Xianjun,
Lu Liujia,
Wang Lingzhi,
Zhang Jinlong
Publication year - 2015
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201500267
Subject(s) - mesoporous material , methylene blue , aqueous solution , composite number , chemistry , adsorption , chemical engineering , mesoporous silica , nanotechnology , nuclear chemistry , materials science , organic chemistry , composite material , catalysis , photocatalysis , engineering
A facile self‐assembly synthetic procedure was exploited to fabricate mesoporous‐silica‐capped Fe 3 O 4 mesoporous clusters, so‐called bimodal mesoporous Fe 3 O 4 @SiO 2 composites. Structural characterization demonstrated that the core of the Fe 3 O 4 clusters is coated with a mesoporous silica shell of uniform size distribution. Moreover, unprecedentedly good tunability of the core size (180–1700 nm) and the shell thickness (20–75 nm) is achievable by changing the synthetic parameters. Application of the composite in the removal of the organic dye methylene blue (MB) from aqueous solution was examined. The composite exhibits excellent adsorption of methylene blue from aqueous solution (33.12 mg g –1 ) within 5 min and is easily regenerated by the photo‐Fenton degradation reaction as a result of its high specific surface area, accessible pore channels, and good magnetic separation properties. This novel adsorbent promises extensive application in the practical removal of organic dyes.