A Disk‐Like Co II  3 Dy III  4  Coordination Cluster Exhibiting Single Molecule Magnet Behavior | Zendy

Loukopoulos Edward | Zendy; Berkoff Benjamin | Zendy; AbdulSada Alaa | Zendy; Tizzard Graham J. | Zendy; Coles Simon J. | Zendy; Escuer Albert | Zendy; Kostakis George E. | Zendy

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A Disk‐Like Co II 3 Dy III 4 Coordination Cluster Exhibiting Single Molecule Magnet Behavior

Author(s) -

Loukopoulos Edward,

Berkoff Benjamin,

AbdulSada Alaa,

Tizzard Graham J.,

Coles Simon J.,

Escuer Albert,

Kostakis George E.

Publication year - 2015

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201500241

Subject(s) - chemistry , cluster (spacecraft) , crystallography , molecule , ligand (biochemistry) , magnetism , coordination complex , single molecule magnet , cluster chemistry , lanthanide , dysprosium , ion , inorganic chemistry , magnetization , metal , physics , organic chemistry , biochemistry , receptor , quantum mechanics , computer science , magnetic field , programming language

The employment of ( E )‐4‐(2‐hydroxy‐3‐methoxybenzylideneamino)‐2,3‐dimethyl‐1‐phenyl‐1,2‐dihydropyrazol‐5‐one (HL) for the first time in 3d/4f chemistry, without any co‐ligand, provides access to a disk‐like heptanuclear Co II 3 Dy III 4 coordination cluster displaying single molecule magnetism (SMM) behavior. The topology of this compound has hitherto not been observed in Co II /Dy III chemistry.

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