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A Disk‐Like Co II 3 Dy III 4 Coordination Cluster Exhibiting Single Molecule Magnet Behavior
Author(s) -
Loukopoulos Edward,
Berkoff Benjamin,
AbdulSada Alaa,
Tizzard Graham J.,
Coles Simon J.,
Escuer Albert,
Kostakis George E.
Publication year - 2015
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201500241
Subject(s) - chemistry , cluster (spacecraft) , crystallography , molecule , ligand (biochemistry) , magnetism , coordination complex , single molecule magnet , cluster chemistry , lanthanide , dysprosium , ion , inorganic chemistry , magnetization , metal , physics , organic chemistry , biochemistry , receptor , quantum mechanics , computer science , magnetic field , programming language
The employment of ( E )‐4‐(2‐hydroxy‐3‐methoxybenzylideneamino)‐2,3‐dimethyl‐1‐phenyl‐1,2‐dihydropyrazol‐5‐one (HL) for the first time in 3d/4f chemistry, without any co‐ligand, provides access to a disk‐like heptanuclear Co II 3 Dy III 4 coordination cluster displaying single molecule magnetism (SMM) behavior. The topology of this compound has hitherto not been observed in Co II /Dy III chemistry.