Phosphaindazole: A Phosphorus–Carbon Aromatic Heterocycle | Zendy

Jevtovikj Ivana | Zendy; Sárosi Menyhárt B. | Zendy; Adhikari Anup K. | Zendy; Lönnecke Peter | Zendy; HeyHawkins Evamarie | Zendy

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Phosphaindazole: A Phosphorus–Carbon Aromatic Heterocycle

Author(s) -

Jevtovikj Ivana,

Sárosi Menyhárt B.,

Adhikari Anup K.,

Lönnecke Peter,

HeyHawkins Evamarie

Publication year - 2015

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201500172

Subject(s) - chemistry , indazole , indene , phosphorus , carbon fibers , medicinal chemistry , sodium , organic chemistry , stereochemistry , materials science , composite number , composite material

A straightforward synthetic route to a novel phosphorus–carbon heterocycle, namely, phosphaindazole, which is the phosphorus analogue of indazole or indene, was developed from sodium tetraphosphanediide [Na 2 (P 4 Mes 4 )](Mes = 2,4,6‐Me 3 C 6 H 2 ) and n BuLi. A proposed intermediate in this reaction, the dimesityldiphosphanide dianion, could be isolated and structurally characterized as [Na 8 (thf) 8 (P 2 Mes 2 ) 4 ] · 2THF.

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